Tetrabutylammonium bromide (TBABr)-based deep eutectic solvents (DESs) and their physical properties.
نویسندگان
چکیده
Density, viscosity and ionic conductivity data sets of deep eutectic solvents (DESs) formed by tetrabutylammonium bromide (TBABr) paired with ethlyene glycol, 1,3-propanediol, 1,5-pentanediol and glycerol hydrogen bond donors (HBDs) are reported. The properties of DES were measured at temperatures between 303 K and 333 K for HBD percentages of 66.7% to 90%. The effects of HBDs under different temperature and percentages are systematically analyzed. As expected, the measured density and viscosity of the studied DESs decreased with an increase in temperature, while ionic conductivity increases with temperature. In general, DESs made of TBABr and glycerol showed the highest density and viscosity and the lowest ionic conductivity when compared to other DESs. The presence of an extra hydroxyl group on glycerol in a DES affected the properties of the DES.
منابع مشابه
Effects of deep eutectic solvents in preparation of nanoparticles TiO2
Deep eutectic solvents (DESs) have always been attractive to scientists due to their wide range of applications, a great interest in diverse fields including nanotechnology due to their unique properties as new green solvents. It used large-scale for chemical and electrochemical synthesis nanomaterial. DESs have had also active role in improving the size and morphology of nanomaterial during sy...
متن کاملEffects of deep eutectic solvents in preparation of nanoparticles TiO2
Deep eutectic solvents (DESs) have always been attractive to scientists due to their wide range of applications, a great interest in diverse fields including nanotechnology due to their unique properties as new green solvents. It used large-scale for chemical and electrochemical synthesis nanomaterial. DESs have had also active role in improving the size and morphology of nanomaterial during sy...
متن کاملRETRACTED: Neoteric FT-IR investigation on the functional groups of phosphonium-based deep eutectic solvents.
Deep eutectic solvents (DESs) are novel solvent media that are currently under investigation as an alternative to ionic liquids and conventional solvents. The physical properties of DESs as well as their mild environmental footprint and potentially critical industrial application necessitate understanding the interaction of functional groups on both the salt and hydrogen bond donor (HBD). In th...
متن کاملMixing cations with different alkyl chain lengths markedly depresses the melting point in deep eutectic solvents formed from alkylammonium bromide salts and urea.
The melting point of a deep eutectic solvent formed from a ternary mixture of ethylammonium bromide (EABr), butylammonium bromide (BABr) and urea is 10 °C, which is almost 40 °C lower than the melting points of binary DESs formed from either EABr:urea or BABr:urea mixtures. This reveals a new route to prepare room temperature DESs via mixing different cations.
متن کاملRecent progress on deep eutectic solvents in biocatalysis
Deep eutectic solvents (DESs) are eutectic mixtures of salts and hydrogen bond donors with melting points low enough to be used as solvents. DESs have proved to be a good alternative to traditional organic solvents and ionic liquids (ILs) in many biocatalytic processes. Apart from the benign characteristics similar to those of ILs (e.g., low volatility, low inflammability and low melting point)...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Molecules
دوره 19 6 شماره
صفحات -
تاریخ انتشار 2014